8 pin motherboard GPU slot design
8 pin motherboard GPU slot design
Based on the design, this appears to be an EPS 12V port rather than a PCIe connection. The CPU power cable should fit. Yet since it lists "gpu_pwr" and both have 8 pins (one 4+4, the other 6+2), their pin layouts differ. Mismatching them could cause issues—magic smoke might appear if connected incorrectly. I’d review the manual thoroughly before proceeding.
Couldn't get it working, so I've temporarily used my old PSU while troubleshooting. Yes, it's an Alienware unit. After disconnecting it, the PC boots up but the GPU isn't receiving power. It's connected via the GPU to the PSU in the right slot. Right now I'm unsure if the PSU is faulty or if the motherboard is acting strangely. I haven't had any problems before, so it probably isn't the board. Any advice would be greatly appreciated. If not, I think I'll return this PSU.